Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice

Parthasarathi Dastidar; Israel Goldberg

doi:10.1107/S0108270196002338

Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice

Parthasarathi Dastidar^*
, Israel Goldberg

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C₄₈H₃₆N₄)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C₄₈H₃₆N₄)].C₇H₇Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.

Original language	English
Pages (from-to)	1976-1980
Number of pages	5
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	8
DOIs	https://doi.org/10.1107/S0108270196002338
State	Published - 15 Aug 1996

Access to Document

10.1107/S0108270196002338

Cite this

@article{474767ea4c2f4642978681d1b70c69a9,

title = "Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice",

abstract = "The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C48H36N4)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C48H36N4)].C7H7Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.",

author = "Parthasarathi Dastidar and Israel Goldberg",

year = "1996",

month = aug,

day = "15",

doi = "10.1107/S0108270196002338",

language = "אנגלית",

volume = "52",

pages = "1976--1980",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "8",

}

Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice. / Dastidar, Parthasarathi; Goldberg, Israel.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 8, 15.08.1996, p. 1976-1980.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice

AU - Dastidar, Parthasarathi

AU - Goldberg, Israel

PY - 1996/8/15

Y1 - 1996/8/15

N2 - The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C48H36N4)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C48H36N4)].C7H7Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.

AB - The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C48H36N4)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C48H36N4)].C7H7Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.

UR - https://www.scopus.com/pages/publications/0030211510

U2 - 10.1107/S0108270196002338

DO - 10.1107/S0108270196002338

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0030211510

SN - 0108-2701

VL - 52

SP - 1976

EP - 1980

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 8

ER -

Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice

Abstract

Access to Document

Other files and links

Fingerprint

Cite this