TY - JOUR
T1 - Zinc-meso-tetra-p-tolylporphyrin and its chlorotoluene channel-type clathrate with π-π and C-H⋯π interaction modes stabilizing the porphyrin host lattice
AU - Dastidar, Parthasarathi
AU - Goldberg, Israel
PY - 1996/8/15
Y1 - 1996/8/15
N2 - The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C48H36N4)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C48H36N4)].C7H7Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.
AB - The title compound, (meso-5,10,15,20-tetra-p-tolylporphyrinato-N,N′,N″,N‴) zinc(II), [Zn(C48H36N4)], displays a high tendency to form complexes and clathrates with other components from various environ-ments, and is a useful building block for the construction of heteromolecular solids. Modes of its intermolecular assembly in the pure compound and in its clathrate with m-chlorotoluene, [Zn(C48H36N4)].C7H7Cl, have been characterized by X-ray crystal-structure analysis. The clathrate appears to be stabilized by π-π stacking and cooperative C-H⋯π interactions between the tolyl substituents and contains large interporphyrin channels extending throughout the crystal.
UR - http://www.scopus.com/inward/record.url?scp=0030211510&partnerID=8YFLogxK
U2 - 10.1107/S0108270196002338
DO - 10.1107/S0108270196002338
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AN - SCOPUS:0030211510
SN - 0108-2701
VL - 52
SP - 1976
EP - 1980
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 8
ER -