TY - JOUR
T1 - Widening the alkyl hypofluorite family. On the existence of ethyl hypofluorite
AU - Rozen, Shlomo
AU - Bar-Haim, Arie
PY - 1995/10
Y1 - 1995/10
N2 - Unlike methanol and t-butanol, most other alcohols do not form alkyl hypofluorites when reacting with fluorine, since immediate HF elimination takes place even at low temperatures. Notable exceptions to this trend are the two deuterated ethanols CD3CD2OD and CH3CD2OH, which do produce the corresponding hypofluorites. Their identification and some of the reasons for this exclusive behavior are outlined.
AB - Unlike methanol and t-butanol, most other alcohols do not form alkyl hypofluorites when reacting with fluorine, since immediate HF elimination takes place even at low temperatures. Notable exceptions to this trend are the two deuterated ethanols CD3CD2OD and CH3CD2OH, which do produce the corresponding hypofluorites. Their identification and some of the reasons for this exclusive behavior are outlined.
KW - Alkyl hypofluorites
KW - Deuterated ethyl hypofluorite
KW - NMR spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=0037891245&partnerID=8YFLogxK
U2 - 10.1016/0022-1139(95)03283-J
DO - 10.1016/0022-1139(95)03283-J
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AN - SCOPUS:0037891245
SN - 0022-1139
VL - 74
SP - 229
EP - 231
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
IS - 2
ER -