Water-soluble manganese(III) corroles and corresponding (nitrido)manganese(V) complexes

Irena Saltsman, Israel Goldberg, Zeev Gross

Research output: Contribution to journalArticlepeer-review

Abstract

Corroles that carry either two or three ortho-pyridyl groups at the meso-carbon atoms form stable manganese(III) complexes, from which corresponding water-soluble derivatives are obtained via N-alkylation. These syntheses and the spectroscopic features are disclosed, together with the molecular structure of the manganese(III) corrole that carries three ortho-pyridylium groups. All the manganese(III) corroles may be transformed to stable (nitrido)manganese(V) complexes, whose NMR spectra provide invaluable structural information regarding the identity and number of atropoisomers.

Original languageEnglish
Pages (from-to)615-620
Number of pages6
JournalJournal of Porphyrins and Phthalocyanines
Volume14
Issue number7
DOIs
StatePublished - Jul 2010

Keywords

  • NMR
  • X-ray crystallography
  • corroles
  • manganese
  • synthesis

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