Voltage-driven changes in molecular dipoles yield negative differential resistance at room temperature

Yoram Selzer; Adi Salomon; Jamal Ghabboun; David Cahen

doi:10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N

Voltage-driven changes in molecular dipoles yield negative differential resistance at room temperature

Yoram Selzer^*, Adi Salomon, Jamal Ghabboun, David Cahen

^*Corresponding author for this work

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Junction function: Molecule-controlled devices based on metal-semiconductor junctions can exhibit negative differential resistance (NDR) at room temperature. The active component is a self-assembled monolayer of molecular dipoles (see schematic representation; X = CF₃, CN, H, OMe). A systematic change in the dipole moment of these molecules results in a corresponding systematic change in the NDR effect, thus establishing for the first time molecularly tunable NDR.

Original language	English
Pages (from-to)	827-830
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	41
Issue number	5
DOIs	https://doi.org/10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N
State	Published - 1 Mar 2002
Externally published	Yes

Keywords

Mercury
Molecular devices
Monolayers
Self-assembly
Semiconductors
Umpolung

Access to Document

10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N

Cite this

@article{be9019c79fa04a1f8be5d793b4ee8c4b,

title = "Voltage-driven changes in molecular dipoles yield negative differential resistance at room temperature",

abstract = "Junction function: Molecule-controlled devices based on metal-semiconductor junctions can exhibit negative differential resistance (NDR) at room temperature. The active component is a self-assembled monolayer of molecular dipoles (see schematic representation; X = CF3, CN, H, OMe). A systematic change in the dipole moment of these molecules results in a corresponding systematic change in the NDR effect, thus establishing for the first time molecularly tunable NDR.",

keywords = "Mercury, Molecular devices, Monolayers, Self-assembly, Semiconductors, Umpolung",

author = "Yoram Selzer and Adi Salomon and Jamal Ghabboun and David Cahen",

year = "2002",

month = mar,

day = "1",

doi = "10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N",

language = "אנגלית",

volume = "41",

pages = "827--830",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "5",

}

TY - JOUR

T1 - Voltage-driven changes in molecular dipoles yield negative differential resistance at room temperature

AU - Selzer, Yoram

AU - Salomon, Adi

AU - Ghabboun, Jamal

AU - Cahen, David

PY - 2002/3/1

Y1 - 2002/3/1

N2 - Junction function: Molecule-controlled devices based on metal-semiconductor junctions can exhibit negative differential resistance (NDR) at room temperature. The active component is a self-assembled monolayer of molecular dipoles (see schematic representation; X = CF3, CN, H, OMe). A systematic change in the dipole moment of these molecules results in a corresponding systematic change in the NDR effect, thus establishing for the first time molecularly tunable NDR.

AB - Junction function: Molecule-controlled devices based on metal-semiconductor junctions can exhibit negative differential resistance (NDR) at room temperature. The active component is a self-assembled monolayer of molecular dipoles (see schematic representation; X = CF3, CN, H, OMe). A systematic change in the dipole moment of these molecules results in a corresponding systematic change in the NDR effect, thus establishing for the first time molecularly tunable NDR.

KW - Mercury

KW - Molecular devices

KW - Monolayers

KW - Self-assembly

KW - Semiconductors

KW - Umpolung

UR - http://www.scopus.com/inward/record.url?scp=0036495326&partnerID=8YFLogxK

U2 - 10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N

DO - 10.1002/1521-3773(20020301)41:5<827::AID-ANIE827>3.0.CO;2-N

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0036495326

SN - 1433-7851

VL - 41

SP - 827

EP - 830

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 5

ER -

Voltage-driven changes in molecular dipoles yield negative differential resistance at room temperature

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this