Vibration-vibration energy transfer in gaseous HBr

I. Burak; Y. Noter; A. M. Ronn; A. Szöke

doi:10.1016/0009-2614(72)80279-3

Vibration-vibration energy transfer in gaseous HBr

I. Burak^*, Y. Noter, A. M. Ronn, A. Szöke

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The vibration-vibration energy transfer of HBr gas initially excited to the first vibrational state has been observed. Collisional pumping to the V = 2 level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process: HBr(V=0) + HBr(V=2) → 2HBr(V=1) is found to be 1.4×10⁵ sec^-1 torr^-1.

Original language	English
Pages (from-to)	306-309
Number of pages	4
Journal	Chemical Physics Letters
Volume	16
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(72)80279-3
State	Published - 1 Oct 1972

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title = "Vibration-vibration energy transfer in gaseous HBr",

abstract = "The vibration-vibration energy transfer of HBr gas initially excited to the first vibrational state has been observed. Collisional pumping to the V = 2 level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process: HBr(V=0) + HBr(V=2) → 2HBr(V=1) is found to be 1.4×105 sec-1 torr-1.",

author = "I. Burak and Y. Noter and Ronn, {A. M.} and A. Sz{\"o}ke",

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AU - Burak, I.

AU - Noter, Y.

AU - Ronn, A. M.

AU - Szöke, A.

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Y1 - 1972/10/1

N2 - The vibration-vibration energy transfer of HBr gas initially excited to the first vibrational state has been observed. Collisional pumping to the V = 2 level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process: HBr(V=0) + HBr(V=2) → 2HBr(V=1) is found to be 1.4×105 sec-1 torr-1.

AB - The vibration-vibration energy transfer of HBr gas initially excited to the first vibrational state has been observed. Collisional pumping to the V = 2 level is measured by monitoring the fluorescence of the 2-1 transition. The rate constant for the process: HBr(V=0) + HBr(V=2) → 2HBr(V=1) is found to be 1.4×105 sec-1 torr-1.

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ER -

Vibration-vibration energy transfer in gaseous HBr

Abstract

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