Versatile supramolecular reactivity of zinc-tetra(4-pyridyl)porphyrin in crystalline solids: Polymeric grids with zinc dichloride and hydrogen-bonded networks with mellitic acid

Sophia Lipstman; Israel Goldberg

doi:10.3762/bjoc.5.77

Versatile supramolecular reactivity of zinc-tetra(4-pyridyl)porphyrin in crystalline solids: Polymeric grids with zinc dichloride and hydrogen-bonded networks with mellitic acid

Sophia Lipstman, Israel Goldberg

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Crystal engineering studies confirm that the zinc-tetra(4-pyridyl)porphyrin building block reveals versatile supramolecular chemistry. In this work, it was found to be reactive in the assembly of both (a) a 2D polymeric array by a unique combination of selfcoordination and coordination through external zinc dichloride linkers and (b) an extended heteromolecular hydrogen-bonded network with mellitic acid sustained by multiple connectivity between the component species.

Original language	English
Article number	77
Journal	Beilstein Journal of Organic Chemistry
Volume	5
DOIs	https://doi.org/10.3762/bjoc.5.77
State	Published - 11 Dec 2009

Keywords

Coordination polymers
Crystal engineering
Hydrogen-bonded networks
Porphyrin assemblies
Supramolecular chemistry

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10.3762/bjoc.5.77

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keywords = "Coordination polymers, Crystal engineering, Hydrogen-bonded networks, Porphyrin assemblies, Supramolecular chemistry",

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KW - Hydrogen-bonded networks

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Versatile supramolecular reactivity of zinc-tetra(4-pyridyl)porphyrin in crystalline solids: Polymeric grids with zinc dichloride and hydrogen-bonded networks with mellitic acid

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Keywords

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