Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes

Ina S. Dubinsky-Davidchik, Israel Goldberg, Arkadi Vigalok*, Andrei N. Vedernikov

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Electrophilic fluorination of aryl α-naphthyl Pt(ii) complexes leads to an unprecedented 1,3-migration of the aryl ligand to the β-position of the naphthyl group. The reaction proceeds via the initial oxidative addition of two fluoro ligands to the Pt center followed by C(sp2)-C(sp2) coupling and aryl migration.

Original languageEnglish
Pages (from-to)3446-3448
Number of pages3
JournalChemical Communications
Volume49
Issue number33
DOIs
StatePublished - 28 Mar 2013

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