TY - JOUR
T1 - Unprecedented 1,3-migration of the aryl ligand in metallacyclic aryl α-naphthyl Pt(iv) difluorides to produce β-arylnaphthyl Pt(ii) complexes
AU - Dubinsky-Davidchik, Ina S.
AU - Goldberg, Israel
AU - Vigalok, Arkadi
AU - Vedernikov, Andrei N.
PY - 2013/3/28
Y1 - 2013/3/28
N2 - Electrophilic fluorination of aryl α-naphthyl Pt(ii) complexes leads to an unprecedented 1,3-migration of the aryl ligand to the β-position of the naphthyl group. The reaction proceeds via the initial oxidative addition of two fluoro ligands to the Pt center followed by C(sp2)-C(sp2) coupling and aryl migration.
AB - Electrophilic fluorination of aryl α-naphthyl Pt(ii) complexes leads to an unprecedented 1,3-migration of the aryl ligand to the β-position of the naphthyl group. The reaction proceeds via the initial oxidative addition of two fluoro ligands to the Pt center followed by C(sp2)-C(sp2) coupling and aryl migration.
UR - http://www.scopus.com/inward/record.url?scp=84876579912&partnerID=8YFLogxK
U2 - 10.1039/c3cc41079j
DO - 10.1039/c3cc41079j
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AN - SCOPUS:84876579912
SN - 1359-7345
VL - 49
SP - 3446
EP - 3448
JO - Chemical Communications
JF - Chemical Communications
IS - 33
ER -