Unexpected PtII migration between the calixarene oxygen atoms

Natalie Kotzen; Israel Goldberg; Sofia Lipstman; Arkadi Vigalok

doi:10.1021/ic0606126

Unexpected Pt^II migration between the calixarene oxygen atoms

Natalie Kotzen, Israel Goldberg, Sofia Lipstman, Arkadi Vigalok^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Reaction between the 1,3-bis(trimethylsilyl) ether of calix[4]arene and platinum(II) difluoro complexes unexpectedly results in the formation of the 1,2-bridging platinum(II) calixarene complex, which, upon treatment with 2 equiv of acyl chloride, reinstates the 1,3-disubstitution pattern in the calixarene moiety.

Original language	English
Pages (from-to)	5266-5268
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	14
DOIs	https://doi.org/10.1021/ic0606126
State	Published - 10 Jul 2006

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title = "Unexpected PtII migration between the calixarene oxygen atoms",

abstract = "Reaction between the 1,3-bis(trimethylsilyl) ether of calix[4]arene and platinum(II) difluoro complexes unexpectedly results in the formation of the 1,2-bridging platinum(II) calixarene complex, which, upon treatment with 2 equiv of acyl chloride, reinstates the 1,3-disubstitution pattern in the calixarene moiety.",

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AU - Kotzen, Natalie

AU - Goldberg, Israel

AU - Lipstman, Sofia

AU - Vigalok, Arkadi

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Y1 - 2006/7/10

N2 - Reaction between the 1,3-bis(trimethylsilyl) ether of calix[4]arene and platinum(II) difluoro complexes unexpectedly results in the formation of the 1,2-bridging platinum(II) calixarene complex, which, upon treatment with 2 equiv of acyl chloride, reinstates the 1,3-disubstitution pattern in the calixarene moiety.

AB - Reaction between the 1,3-bis(trimethylsilyl) ether of calix[4]arene and platinum(II) difluoro complexes unexpectedly results in the formation of the 1,2-bridging platinum(II) calixarene complex, which, upon treatment with 2 equiv of acyl chloride, reinstates the 1,3-disubstitution pattern in the calixarene moiety.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Unexpected Pt^II migration between the calixarene oxygen atoms

Abstract

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