Ultrafast spectroscopy of solvation dynamics: From linear to nonlinear solvation study

B. D. Fainberg; B. Zolotov; A. Gan; D. Huppert

doi:10.1109/eqec.1996.561894

Ultrafast spectroscopy of solvation dynamics: From linear to nonlinear solvation study

B. D. Fainberg^*, B. Zolotov, A. Gan, D. Huppert

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to conference › Paper › peer-review

Abstract

The solvation dynamics of two organic molecules, namely rhodamine and cryptocianine in normal and deuterated water, was studied using ultrafast four-photon spectroscopy with pulses longer than the electronic transition dephasing. The isotope effect on solvation dynamics of solutes in H₂O and D₂O was measured. The shapes of solvation correlation functions were obtained by fitting the experimental data with the theoretical model calculations. It has been demonstrated that, depending on the excitation frequency, different methods of transient four-photon spectroscopy can provide information concerning the solvation dynamics either in the ground or in the excited electronic states of the solute.

Original language	English
Pages	213
Number of pages	1
DOIs	https://doi.org/10.1109/eqec.1996.561894
State	Published - 1996
Event	Proceedings of the 1996 European Quantum Electronics Conference, EQEC'96 - Hamburg, Ger Duration: 8 Sep 1996 → 13 Sep 1996

Conference

Conference	Proceedings of the 1996 European Quantum Electronics Conference, EQEC'96
City	Hamburg, Ger
Period	8/09/96 → 13/09/96

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10.1109/eqec.1996.561894

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abstract = "The solvation dynamics of two organic molecules, namely rhodamine and cryptocianine in normal and deuterated water, was studied using ultrafast four-photon spectroscopy with pulses longer than the electronic transition dephasing. The isotope effect on solvation dynamics of solutes in H2O and D2O was measured. The shapes of solvation correlation functions were obtained by fitting the experimental data with the theoretical model calculations. It has been demonstrated that, depending on the excitation frequency, different methods of transient four-photon spectroscopy can provide information concerning the solvation dynamics either in the ground or in the excited electronic states of the solute.",

author = "Fainberg, {B. D.} and B. Zolotov and A. Gan and D. Huppert",

year = "1996",

doi = "10.1109/eqec.1996.561894",

language = "אנגלית",

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note = "Proceedings of the 1996 European Quantum Electronics Conference, EQEC'96 ; Conference date: 08-09-1996 Through 13-09-1996",

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AU - Fainberg, B. D.

AU - Zolotov, B.

AU - Gan, A.

AU - Huppert, D.

PY - 1996

Y1 - 1996

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AB - The solvation dynamics of two organic molecules, namely rhodamine and cryptocianine in normal and deuterated water, was studied using ultrafast four-photon spectroscopy with pulses longer than the electronic transition dephasing. The isotope effect on solvation dynamics of solutes in H2O and D2O was measured. The shapes of solvation correlation functions were obtained by fitting the experimental data with the theoretical model calculations. It has been demonstrated that, depending on the excitation frequency, different methods of transient four-photon spectroscopy can provide information concerning the solvation dynamics either in the ground or in the excited electronic states of the solute.

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Y2 - 8 September 1996 through 13 September 1996

ER -

Ultrafast spectroscopy of solvation dynamics: From linear to nonlinear solvation study

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