TY - JOUR
T1 - Two open-framework zinc phosphites constructed from different secondary building units
AU - Luan, Lindong
AU - Zhang, Wei
AU - Wang, Kangcai
AU - Lin, Zhien
AU - Huang, Hui
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/10/1
Y1 - 2016/10/1
N2 - Presented here are two new zinc phosphites, formulate as Zn3(dabco)2(HPO3)3 (1, dabco = 1,4-diazabicyclo[2·2·2]octane), and H2pmdeta ⋅ Zn3(HPO3)4 (2, pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine). Compound 1 has 12-membered-ring (12 MR) channels with a 5-connected bnn topology containing 4 = 1 secondary building units. Compound 2 has multidirectional 10 MR channels with a pcu topology constructed from 6*1 secondary building units. The gas adsorption and fluorescent properties of compound 1 were also investigated.
AB - Presented here are two new zinc phosphites, formulate as Zn3(dabco)2(HPO3)3 (1, dabco = 1,4-diazabicyclo[2·2·2]octane), and H2pmdeta ⋅ Zn3(HPO3)4 (2, pmdeta = N,N,N′,N″,N″-pentamethyldiethylenetriamine). Compound 1 has 12-membered-ring (12 MR) channels with a 5-connected bnn topology containing 4 = 1 secondary building units. Compound 2 has multidirectional 10 MR channels with a pcu topology constructed from 6*1 secondary building units. The gas adsorption and fluorescent properties of compound 1 were also investigated.
KW - Gas adsorption
KW - Open-framework materials
KW - Secondary building unit
KW - Topology
KW - Zinc phosphites
UR - http://www.scopus.com/inward/record.url?scp=84984621851&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.08.025
DO - 10.1016/j.inoche.2016.08.025
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AN - SCOPUS:84984621851
SN - 1387-7003
VL - 72
SP - 96
EP - 99
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
ER -