T1 Spin decoupling effects on the lineshapes of NMR spin-spin multiplets

G. Navon*, M. Polak

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

T1 relaxation of one set of nuclei causes an extra-broadening and an apparent reduction of the spin-spin splitting in the NMR spectrum of another set of nuclei coupled to it. These effects are demonstrated by line-shape calculations for first order multiplets of spin 1 2 nuclei. It is shown that in a well-resolved multiplet of nuclei A in AmXn spectra the extra-broadening of each component is given by n/2T1X.

Original languageEnglish
Pages (from-to)239-242
Number of pages4
JournalChemical Physics Letters
Volume25
Issue number2
DOIs
StatePublished - 15 Mar 1974

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