Abstract
T1 relaxation of one set of nuclei causes an extra-broadening and an apparent reduction of the spin-spin splitting in the NMR spectrum of another set of nuclei coupled to it. These effects are demonstrated by line-shape calculations for first order multiplets of spin 1 2 nuclei. It is shown that in a well-resolved multiplet of nuclei A in AmXn spectra the extra-broadening of each component is given by n/2T1X.
Original language | English |
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Pages (from-to) | 239-242 |
Number of pages | 4 |
Journal | Chemical Physics Letters |
Volume | 25 |
Issue number | 2 |
DOIs | |
State | Published - 15 Mar 1974 |