Trace Organic Compound Removal from Wastewater Reverse-Osmosis Concentrate by Advanced Oxidation Processes with UV/O3/H2O2

Advanced technologies, such as reverse osmosis (RO), allow the reuse of treated wastewater for direct or indirect potable use. However, even highly efficient RO systems produce ~10–15% highly contaminated concentrate as a byproduct. This wastewater RO concentrate (WWROC) is very rich in metal ions, nutrients, and hard-to-degrade trace organic compounds (TOrCs), such as pharmaceuticals, plasticizers, flame retardants, and detergents, which must be treated before disposal. WWROC could be up to 10 times more concentrated than secondary effluent. We examined the efficiency of several advanced oxidation processes (AOPs) on TOrC removal from a two-stage WWROC matrix in a pilot wastewater-treatment facility. WWROC ozonation or UV irradiation, with H₂O₂ addition, demonstrated efficient removal of TOrCs, varying between 21% and over 99% degradation, and indicating that radical oxidation (by HO·) is the dominant mechanism. However, AOPs are not sufficient to fully treat the WWROC, and thus, additional procedures are required to decrease metal ion and nutrient concentrations. Further biological treatment post-AOP is also highly important, to eliminate the degradable organic molecules obtained from the AOP.