Titanium complexes of chelating dianionic amine bis(phenolate) ligands: An extra donor makes a big difference

Edit Y. Tshuva, Miriam Versano, Israel Goldberg, Moshe Kol, Hana Weitman, Zeev Goldschmidt

Research output: Contribution to journalArticlepeer-review

Abstract

Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig2Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPri)2 type complex.

Original languageEnglish
Pages (from-to)371-373
Number of pages3
JournalInorganic Chemistry Communication
Volume2
Issue number8
DOIs
StatePublished - 1 Aug 1999

Keywords

  • Crystal structures
  • Octahedral geometry
  • Phenolate ligands
  • Titanium complexes

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