Thermodynamic properties of hydrated and ammoniated electrons

Gerard Lepoutre, Joshua Jortner

Research output: Contribution to journalArticlepeer-review

Abstract

We have found fair agreement between the free enthalpies of solvated electrons as computed from experimental data and from theoretical models. The apparent anomalies in the entropy of the ammoniated electron are due to a looser packing in the first solvation layer relative to the pure solvent, this effect being larger at a lower temperature. Some spectroscopic results can be rationalized in terms of the thermodynamic data.

Original languageEnglish
Pages (from-to)683-687
Number of pages5
JournalJournal of Physical Chemistry
Volume76
Issue number5
DOIs
StatePublished - 1972

Fingerprint

Dive into the research topics of 'Thermodynamic properties of hydrated and ammoniated electrons'. Together they form a unique fingerprint.

Cite this