TY - JOUR
T1 - Thermal and Photochemical Transformation Modes of Cyclopentadienone‐Dimers
T2 - Structural and Stereochemical Aspects
AU - Fuchs, Benzion
PY - 1980
Y1 - 1980
N2 - Schemes are presented describing all possible rearrangement modes of cyclopentadienone‐dimers, the basic assumption being intramolecularity and C6‐C7 bond breaking in the (4π + 2π) dimers. For the endo‐dimer (2) all theoretically possible transformations (Fig. 1) are backed up by experiment. In the exo‐dimer (9) series (Fig. 3), some still await detection. Symmetry and stereochemical features are emphasized, as they enter structural and mechanistic considerations.
AB - Schemes are presented describing all possible rearrangement modes of cyclopentadienone‐dimers, the basic assumption being intramolecularity and C6‐C7 bond breaking in the (4π + 2π) dimers. For the endo‐dimer (2) all theoretically possible transformations (Fig. 1) are backed up by experiment. In the exo‐dimer (9) series (Fig. 3), some still await detection. Symmetry and stereochemical features are emphasized, as they enter structural and mechanistic considerations.
UR - http://www.scopus.com/inward/record.url?scp=84985050931&partnerID=8YFLogxK
U2 - 10.1002/ijch.198000073
DO - 10.1002/ijch.198000073
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AN - SCOPUS:84985050931
SN - 0021-2148
VL - 20
SP - 203
EP - 207
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 1-2
ER -