The transition from non-adiabatic to solvent controlled adiabatic electron transfer kinetics. An experimental study

Asnat Masad; Dan Huppert; Edward M. Kosower

doi:10.1016/0301-0104(90)80105-7

The transition from non-adiabatic to solvent controlled adiabatic electron transfer kinetics. An experimental study

Asnat Masad^*, Dan Huppert, Edward M. Kosower

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

At sufficiently high temperatures, the solvent longitudinal dielectric relaxation time τ_L is less than 1 ns; the charge-transfer process converting the S_1,CT to S₀ of arylaminonaphthalenesulfon-N,N-dimethylamide derivatives is controlled by solvent polarity, while at lower temperatures, τ_L is more than 1 ns and controls the rate.

Original language	English
Pages (from-to)	391-400
Number of pages	10
Journal	Chemical Physics
Volume	144
Issue number	3
DOIs	https://doi.org/10.1016/0301-0104(90)80105-7
State	Published - 15 Jul 1990

Funding

Funders	Funder number
James Franck Binational German-Israeli Program in Iaser-Matter Interaction

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10.1016/0301-0104(90)80105-7

Cite this

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title = "The transition from non-adiabatic to solvent controlled adiabatic electron transfer kinetics. An experimental study",

abstract = "At sufficiently high temperatures, the solvent longitudinal dielectric relaxation time τL is less than 1 ns; the charge-transfer process converting the S1,CT to S0 of arylaminonaphthalenesulfon-N,N-dimethylamide derivatives is controlled by solvent polarity, while at lower temperatures, τL is more than 1 ns and controls the rate.",

author = "Asnat Masad and Dan Huppert and Kosower, {Edward M.}",

note = "Funding Information: This work was supported in part by the James Franck Binational German-Israeli Program in Iaser-Matter Interaction.",

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AU - Huppert, Dan

AU - Kosower, Edward M.

N1 - Funding Information: This work was supported in part by the James Franck Binational German-Israeli Program in Iaser-Matter Interaction.

PY - 1990/7/15

Y1 - 1990/7/15

N2 - At sufficiently high temperatures, the solvent longitudinal dielectric relaxation time τL is less than 1 ns; the charge-transfer process converting the S1,CT to S0 of arylaminonaphthalenesulfon-N,N-dimethylamide derivatives is controlled by solvent polarity, while at lower temperatures, τL is more than 1 ns and controls the rate.

AB - At sufficiently high temperatures, the solvent longitudinal dielectric relaxation time τL is less than 1 ns; the charge-transfer process converting the S1,CT to S0 of arylaminonaphthalenesulfon-N,N-dimethylamide derivatives is controlled by solvent polarity, while at lower temperatures, τL is more than 1 ns and controls the rate.

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The transition from non-adiabatic to solvent controlled adiabatic electron transfer kinetics. An experimental study

Abstract

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