The transition from non-adiabatic to solvent controlled adiabatic electron transfer kinetics. An experimental study

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Abstract

At sufficiently high temperatures, the solvent longitudinal dielectric relaxation time τL is less than 1 ns; the charge-transfer process converting the S1,CT to S0 of arylaminonaphthalenesulfon-N,N-dimethylamide derivatives is controlled by solvent polarity, while at lower temperatures, τL is more than 1 ns and controls the rate.

Original languageEnglish
Pages (from-to)391-400
Number of pages10
JournalChemical Physics
Volume144
Issue number3
DOIs
StatePublished - 15 Jul 1990

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