The synthesis of the 9-phosphabicyclo[3.3.1]nonanic and 2-phospha-6-oxaadamantanic systems

Y. Kashman, E. Benary

Research output: Contribution to journalArticlepeer-review

Abstract

Several derivatives of 2-phospha-6-oxaadamantane (8, 9, 10 and 11) have been prepared from suitably substituted 9-phosphabicyclo[3.3.1]nonanes. The bicyclo compounds were synthesized by a double Michael addition of a primary phosphine to 2,7-cyclooctadienone. The stereochemistry of the adducts and related compounds was determined by investigation of their NMR spectra.

Original languageEnglish
Pages (from-to)4083-4089
Number of pages7
JournalTetrahedron
Volume28
Issue number15
DOIs
StatePublished - 1972

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