The synthesis of the 9-phosphabicyclo[3.3.1]nonanic and 2-phospha-6-oxaadamantanic systems

Y. Kashman; E. Benary

doi:10.1016/S0040-4020(01)93639-7

The synthesis of the 9-phosphabicyclo[3.3.1]nonanic and 2-phospha-6-oxaadamantanic systems

Y. Kashman^*, E. Benary

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

Several derivatives of 2-phospha-6-oxaadamantane (8, 9, 10 and 11) have been prepared from suitably substituted 9-phosphabicyclo[3.3.1]nonanes. The bicyclo compounds were synthesized by a double Michael addition of a primary phosphine to 2,7-cyclooctadienone. The stereochemistry of the adducts and related compounds was determined by investigation of their NMR spectra.

Original language	English
Pages (from-to)	4083-4089
Number of pages	7
Journal	Tetrahedron
Volume	28
Issue number	15
DOIs	https://doi.org/10.1016/S0040-4020(01)93639-7
State	Published - 1972

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AB - Several derivatives of 2-phospha-6-oxaadamantane (8, 9, 10 and 11) have been prepared from suitably substituted 9-phosphabicyclo[3.3.1]nonanes. The bicyclo compounds were synthesized by a double Michael addition of a primary phosphine to 2,7-cyclooctadienone. The stereochemistry of the adducts and related compounds was determined by investigation of their NMR spectra.

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The synthesis of the 9-phosphabicyclo[3.3.1]nonanic and 2-phospha-6-oxaadamantanic systems

Abstract

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