Abstract
Several derivatives of 2-phospha-6-oxaadamantane (8, 9, 10 and 11) have been prepared from suitably substituted 9-phosphabicyclo[3.3.1]nonanes. The bicyclo compounds were synthesized by a double Michael addition of a primary phosphine to 2,7-cyclooctadienone. The stereochemistry of the adducts and related compounds was determined by investigation of their NMR spectra.
Original language | English |
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Pages (from-to) | 4083-4089 |
Number of pages | 7 |
Journal | Tetrahedron |
Volume | 28 |
Issue number | 15 |
DOIs | |
State | Published - 1972 |