The Synthesis of 2-Aza-6-oxaadamantane

Y. Kashman; E. Benary

doi:10.1021/jo00797a004

The Synthesis of 2-Aza-6-oxaadamantane

Y. Kashman^*
, E. Benary

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new synthesis of 2-aza-6-oxaadamantane from suitably substituted 9-azabicyclo[3.3.1]nonane (prepared by a double Michael addition of a primary amine to 2,7-cyclooctadienone), has been achieved. The nmr of the various azabicyclic compounds were investigated; J values of the ketones and Tc values of the N-acetyl compounds are discussed.

Original language	English
Pages (from-to)	3778-3781
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	37
Issue number	24
DOIs	https://doi.org/10.1021/jo00797a004
State	Published - 1 Dec 1972

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title = "The Synthesis of 2-Aza-6-oxaadamantane",

abstract = "A new synthesis of 2-aza-6-oxaadamantane from suitably substituted 9-azabicyclo[3.3.1]nonane (prepared by a double Michael addition of a primary amine to 2,7-cyclooctadienone), has been achieved. The nmr of the various azabicyclic compounds were investigated; J values of the ketones and Tc values of the N-acetyl compounds are discussed.",

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N2 - A new synthesis of 2-aza-6-oxaadamantane from suitably substituted 9-azabicyclo[3.3.1]nonane (prepared by a double Michael addition of a primary amine to 2,7-cyclooctadienone), has been achieved. The nmr of the various azabicyclic compounds were investigated; J values of the ketones and Tc values of the N-acetyl compounds are discussed.

AB - A new synthesis of 2-aza-6-oxaadamantane from suitably substituted 9-azabicyclo[3.3.1]nonane (prepared by a double Michael addition of a primary amine to 2,7-cyclooctadienone), has been achieved. The nmr of the various azabicyclic compounds were investigated; J values of the ketones and Tc values of the N-acetyl compounds are discussed.

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The Synthesis of 2-Aza-6-oxaadamantane

Abstract

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