The spectrum and stability of oxygen iodide charge-transfer complex

H. Levanon, G. Navon

Research output: Contribution to journalArticlepeer-review

Abstract

Extra absorption spectra due to oxygen iodide charge-transfer interaction in different solvents were studied. Attempts to determine the stability constant of the O2I- complex led to an upper limit of K ≤ 0.3 M-1. Heats of formation of 1.2,0.0, and -0.7 kcal in water, ethanol, and ethyleneglycol, respectively, wereobtained. From the solvent dependence of the optical absorption intensity and the heats of formation, an outer-sphere type oxygen iodide complex was proposed. From the energies of the optical transitions, a vertical electron affinity of EO2v < 5 kcal for oxygen was estimated.

Original languageEnglish
Pages (from-to)1861-1868
Number of pages8
JournalJournal of Physical Chemistry
Volume73
Issue number6
DOIs
StatePublished - 1969
Externally publishedYes

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