The role of hydrogen atoms in the decomposition of hydrogen peroxide and in the radiation chemistry of water

Gideon Czapski; Joshua Jortner; Gabriel Stein

doi:10.1021/j100824a018

The role of hydrogen atoms in the decomposition of hydrogen peroxide and in the radiation chemistry of water

Gideon Czapski^*, Joshua Jortner, Gabriel Stein

^*Corresponding author for this work

Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Atomic hydrogen generated by an electrodeless high frequency discharge in H₂ gas and introduced into aqueous solutions reacts with 10^-4-10^-5 M H₂O₂ with a velocity constant of k ≅ 10⁵ liter mole^-1 sec.^-1, unaffected by changing the pH from 1 to 13. The reactions involved are discussed and compared with those postulated for the radiolysis of aqueous H₂O₂ solutions.

Original language	English
Pages (from-to)	964-966
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	65
Issue number	6
DOIs	https://doi.org/10.1021/j100824a018
State	Published - 1961
Externally published	Yes

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title = "The role of hydrogen atoms in the decomposition of hydrogen peroxide and in the radiation chemistry of water",

abstract = "Atomic hydrogen generated by an electrodeless high frequency discharge in H2 gas and introduced into aqueous solutions reacts with 10-4-10-5 M H2O2 with a velocity constant of k ≅ 105 liter mole-1 sec.-1, unaffected by changing the pH from 1 to 13. The reactions involved are discussed and compared with those postulated for the radiolysis of aqueous H2O2 solutions.",

author = "Gideon Czapski and Joshua Jortner and Gabriel Stein",

year = "1961",

doi = "10.1021/j100824a018",

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journal = "Journal of Physical Chemistry",

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publisher = "American Chemical Society",

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AU - Czapski, Gideon

AU - Jortner, Joshua

AU - Stein, Gabriel

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AB - Atomic hydrogen generated by an electrodeless high frequency discharge in H2 gas and introduced into aqueous solutions reacts with 10-4-10-5 M H2O2 with a velocity constant of k ≅ 105 liter mole-1 sec.-1, unaffected by changing the pH from 1 to 13. The reactions involved are discussed and compared with those postulated for the radiolysis of aqueous H2O2 solutions.

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JO - Journal of Physical Chemistry

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The role of hydrogen atoms in the decomposition of hydrogen peroxide and in the radiation chemistry of water

Abstract

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