Abstract
The rate constants of the reactions of H atoms (produced by the electrodeless high-frequency dissociation of hydrogen gas) with some high- and low-spin complexes of FeIII were determined. The results are compared with those obtained for related H atom reactions with FeIII complexes, using radiation chemical techniques, with reactions of such complexes with eaq-, and with the rates of reactions of other metal ion complexes. The results are consistent with mechanisms involving H atom addition and, in the case of high-spin complexes, specific effect of the ligands on the resultant electron transfer.
Original language | English |
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Pages (from-to) | 3630-3641 |
Number of pages | 12 |
Journal | Journal of Physical Chemistry |
Volume | 70 |
Issue number | 11 |
DOIs | |
State | Published - 1966 |
Externally published | Yes |