TY - JOUR
T1 - The product state-resolved dynamics of the reaction H + N 2 O → OH( v′,j′ ) + N 2
AU - Brouard, M.
AU - Burak, I.
AU - Gatenby, S. D.
AU - Markillie, G. A.J.
N1 - Funding Information:
We are grateful to the EPSRC for the award of a studentships to SDG and GAJM and funding the visit of IB to the UK.
PY - 1998/5/8
Y1 - 1998/5/8
N2 - The product state-resolved dynamics of the photon-initiated title reaction, leading to the production of OH(X2Π3/2;v′=0,N′=5), has been studied using Doppler-resolved laser-induced fluorescence at a collision energy of 143 kJmol-1 (=1.48eV). The angular distribution of OH(v′=0,N′=5) is found to possess both forward and backward peaks, with a slight bias towards the backward hemisphere. The experiments allow precise determination of the distribution of energy released into translation and hence into the internal modes of the N2 co-product. The OH state specific kinetic energy disposal is found to be sharply distributed about a mean fractional translational energy release ft~0.4. The results are discussed in the light of previous experimental and theoretical work.
AB - The product state-resolved dynamics of the photon-initiated title reaction, leading to the production of OH(X2Π3/2;v′=0,N′=5), has been studied using Doppler-resolved laser-induced fluorescence at a collision energy of 143 kJmol-1 (=1.48eV). The angular distribution of OH(v′=0,N′=5) is found to possess both forward and backward peaks, with a slight bias towards the backward hemisphere. The experiments allow precise determination of the distribution of energy released into translation and hence into the internal modes of the N2 co-product. The OH state specific kinetic energy disposal is found to be sharply distributed about a mean fractional translational energy release ft~0.4. The results are discussed in the light of previous experimental and theoretical work.
UR - http://www.scopus.com/inward/record.url?scp=0032495906&partnerID=8YFLogxK
U2 - 10.1016/S0009-2614(98)00225-5
DO - 10.1016/S0009-2614(98)00225-5
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AN - SCOPUS:0032495906
SN - 0009-2614
VL - 287
SP - 682
EP - 688
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 5-6
ER -