The oxidation of iodide ions in aqueous solution by atomic hydrogen

Gideon Czapski; Joshua Jortner; Gabriel Stein

doi:10.1021/j150580a048

The oxidation of iodide ions in aqueous solution by atomic hydrogen

Gideon Czapski^*, Joshua Jortner, Gabriel Stein

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Iodide ions in aqueous solution are oxidized by atomic hydrogen produced in an electrodeless high frequency discharge and introduced into the solution. The influence of hydrogen ion and iodide ion concentration on the reaction was investigated in the pH range of 0.4-7.0. Various possible mechanisms are discussed and it is shown that of these only the mechanism involving the H⁺_2aq ion as the actual oxidizing species agrees with all the results. Some rate constants are estimated.

Original language	English
Pages (from-to)	1769-1774
Number of pages	6
Journal	Journal of Physical Chemistry
Volume	63
Issue number	10
DOIs	https://doi.org/10.1021/j150580a048
State	Published - 1959
Externally published	Yes

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title = "The oxidation of iodide ions in aqueous solution by atomic hydrogen",

abstract = "Iodide ions in aqueous solution are oxidized by atomic hydrogen produced in an electrodeless high frequency discharge and introduced into the solution. The influence of hydrogen ion and iodide ion concentration on the reaction was investigated in the pH range of 0.4-7.0. Various possible mechanisms are discussed and it is shown that of these only the mechanism involving the H+2aq ion as the actual oxidizing species agrees with all the results. Some rate constants are estimated.",

author = "Gideon Czapski and Joshua Jortner and Gabriel Stein",

year = "1959",

doi = "10.1021/j150580a048",

language = "אנגלית",

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journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - The oxidation of iodide ions in aqueous solution by atomic hydrogen

AU - Czapski, Gideon

AU - Jortner, Joshua

AU - Stein, Gabriel

PY - 1959

Y1 - 1959

N2 - Iodide ions in aqueous solution are oxidized by atomic hydrogen produced in an electrodeless high frequency discharge and introduced into the solution. The influence of hydrogen ion and iodide ion concentration on the reaction was investigated in the pH range of 0.4-7.0. Various possible mechanisms are discussed and it is shown that of these only the mechanism involving the H+2aq ion as the actual oxidizing species agrees with all the results. Some rate constants are estimated.

AB - Iodide ions in aqueous solution are oxidized by atomic hydrogen produced in an electrodeless high frequency discharge and introduced into the solution. The influence of hydrogen ion and iodide ion concentration on the reaction was investigated in the pH range of 0.4-7.0. Various possible mechanisms are discussed and it is shown that of these only the mechanism involving the H+2aq ion as the actual oxidizing species agrees with all the results. Some rate constants are estimated.

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AN - SCOPUS:33947472876

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VL - 63

SP - 1769

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JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 10

ER -

The oxidation of iodide ions in aqueous solution by atomic hydrogen

Abstract

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