The intrinsic viscosity of dilute polymer solutions

Mordechai Bixon

doi:10.1063/1.433869

The intrinsic viscosity of dilute polymer solutions

Mordechai Bixon^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A general formal expression for the intrinsic viscosity of a dilute polymer solution is derived. The derivation is based on projecting the polymer dynamics onto the subspace of bilinear products of coordinates {x_iy _j}. It results in an expression composed of two terms. The first includes most of the low frequency behavior and the second all of the high frequency behavior of stiff polymers. The zero frequency limit and the Gaussian model are evaluated.

Original language	English
Pages (from-to)	5500-5504
Number of pages	5
Journal	The Journal of Chemical Physics
Volume	66
Issue number	12
DOIs	https://doi.org/10.1063/1.433869
State	Published - 1977

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abstract = "A general formal expression for the intrinsic viscosity of a dilute polymer solution is derived. The derivation is based on projecting the polymer dynamics onto the subspace of bilinear products of coordinates {xiy j}. It results in an expression composed of two terms. The first includes most of the low frequency behavior and the second all of the high frequency behavior of stiff polymers. The zero frequency limit and the Gaussian model are evaluated.",

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The intrinsic viscosity of dilute polymer solutions

Abstract

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