TY - JOUR
T1 - The H + H2O → OH + H2 reaction
T2 - OH state-resolved differential cross-sections and H2 internal energy disposals
AU - Brouard, M.
AU - Burak, I.
AU - Markillie, G. A.J.
AU - McGrath, K.
AU - Vallance, C.
N1 - Funding Information:
We are grateful to the EPSRC for a research grant and the award of studentship to GAJM. We also acknowledge very helpful discussions with Professor F.J. Aoiz (Complutense University, Madrid), and thank the Spanish–British exchange program `Acciones Integradas' (FJA) and the EPSRC (IB) for funding their visits to Oxford.
PY - 1997/12/19
Y1 - 1997/12/19
N2 - The OH(2Π1/,2,v′ = 0,N'′= 1) state-resolved differential cross-section and H2 co-product internal energy distribution have been determined experimentally for the hot H-atom reaction with H2O at a mean collision energy of 1.43 eV, using the polarized Doppler-resolved laser induced fluorescence technique. The derived angular distribution shows intensity over a wide range of scattering angles, and the majority (~ 87%) of the energy available to the state specific OH products is channelled into kinetic energy. The results are discussed in the light of other recent experimental and theoretical work on this prototypical four atom reaction.
AB - The OH(2Π1/,2,v′ = 0,N'′= 1) state-resolved differential cross-section and H2 co-product internal energy distribution have been determined experimentally for the hot H-atom reaction with H2O at a mean collision energy of 1.43 eV, using the polarized Doppler-resolved laser induced fluorescence technique. The derived angular distribution shows intensity over a wide range of scattering angles, and the majority (~ 87%) of the energy available to the state specific OH products is channelled into kinetic energy. The results are discussed in the light of other recent experimental and theoretical work on this prototypical four atom reaction.
UR - http://www.scopus.com/inward/record.url?scp=0031579004&partnerID=8YFLogxK
U2 - 10.1016/S0009-2614(97)01158-5
DO - 10.1016/S0009-2614(97)01158-5
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AN - SCOPUS:0031579004
SN - 0009-2614
VL - 281
SP - 97
EP - 104
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1-3
ER -