The first general route for efficient synthesis of 18O labelled alcohols using the HOF·CH3CN complex

Julia Gatenyo; Inna Vints; Shlomo Rozen

doi:10.1039/c3cc42337a

The first general route for efficient synthesis of ¹⁸O labelled alcohols using the HOF·CH₃CN complex

Julia Gatenyo, Inna Vints, Shlomo Rozen^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A mild and very efficient method for converting boronic acids to alcohols has been developed using the acetonitrile complex of hypofluorous acid HOF·CH₃CN. Employing ¹⁸O-labeled water results in alcohols containing a heavy oxygen isotope. The reactions were performed at room temperature, within a few minutes and in excellent yields.

Original language	English
Pages (from-to)	7379-7381
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	67
DOIs	https://doi.org/10.1039/c3cc42337a
State	Published - 25 Jul 2013

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abstract = "A mild and very efficient method for converting boronic acids to alcohols has been developed using the acetonitrile complex of hypofluorous acid HOF·CH3CN. Employing 18O-labeled water results in alcohols containing a heavy oxygen isotope. The reactions were performed at room temperature, within a few minutes and in excellent yields.",

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AB - A mild and very efficient method for converting boronic acids to alcohols has been developed using the acetonitrile complex of hypofluorous acid HOF·CH3CN. Employing 18O-labeled water results in alcohols containing a heavy oxygen isotope. The reactions were performed at room temperature, within a few minutes and in excellent yields.

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The first general route for efficient synthesis of ¹⁸O labelled alcohols using the HOF·CH₃CN complex

Abstract

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