The first general method for α-trifluoromethylation of carboxylic acids using BrF3

Aviv Hagooly; Shlomo Rozen

doi:10.1039/b315705a

The first general method for α-trifluoromethylation of carboxylic acids using BrF₃

Aviv Hagooly, Shlomo Rozen^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

2-Carbomethoxy-1,1-bis(methylsulfide)-1-alkenes, easily made from carboxylic acids, CS₂ and MeI, were treated with BrF₃ producing eventually the desired α-trifluoromethyl carboxylate derivatives - RCH(CF₃)COOR′- in good yields.

Original language	English
Pages (from-to)	594-595
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	5
DOIs	https://doi.org/10.1039/b315705a
State	Published - 2004

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abstract = "2-Carbomethoxy-1,1-bis(methylsulfide)-1-alkenes, easily made from carboxylic acids, CS2 and MeI, were treated with BrF3 producing eventually the desired α-trifluoromethyl carboxylate derivatives - RCH(CF3)COOR′- in good yields.",

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AB - 2-Carbomethoxy-1,1-bis(methylsulfide)-1-alkenes, easily made from carboxylic acids, CS2 and MeI, were treated with BrF3 producing eventually the desired α-trifluoromethyl carboxylate derivatives - RCH(CF3)COOR′- in good yields.

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The first general method for α-trifluoromethylation of carboxylic acids using BrF₃

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