The effect of T1 spin decoupling and chemical exchange on the NMR spectra of first-order multiplets

Moshe Evenor; Gil Navon

doi:10.1016/0022-2364(77)90175-5

The effect of T₁ spin decoupling and chemical exchange on the NMR spectra of first-order multiplets

Moshe Evenor^*, Gil Navon

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The NMR lineshapes of exchanging first-order spin-spin multiplets were calculated, taking into consideration the effect of T₁ spin decoupling. Explicit expressions for line broadening and shift were derived for the system AX ⇄ BY and in one limiting case also for A_mX_n ⇄ B_mY_n, under the conditions where Swift and Connick's equations for single-spin systems are applicable.

Original language	English
Pages (from-to)	291-300
Number of pages	10
Journal	Journal of Magnetic Resonance (1969)
Volume	26
Issue number	2
DOIs	https://doi.org/10.1016/0022-2364(77)90175-5
State	Published - May 1977

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title = "The effect of T1 spin decoupling and chemical exchange on the NMR spectra of first-order multiplets",

abstract = "The NMR lineshapes of exchanging first-order spin-spin multiplets were calculated, taking into consideration the effect of T1 spin decoupling. Explicit expressions for line broadening and shift were derived for the system AX ⇄ BY and in one limiting case also for AmXn ⇄ BmYn, under the conditions where Swift and Connick's equations for single-spin systems are applicable.",

author = "Moshe Evenor and Gil Navon",

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AU - Evenor, Moshe

AU - Navon, Gil

PY - 1977/5

Y1 - 1977/5

N2 - The NMR lineshapes of exchanging first-order spin-spin multiplets were calculated, taking into consideration the effect of T1 spin decoupling. Explicit expressions for line broadening and shift were derived for the system AX ⇄ BY and in one limiting case also for AmXn ⇄ BmYn, under the conditions where Swift and Connick's equations for single-spin systems are applicable.

AB - The NMR lineshapes of exchanging first-order spin-spin multiplets were calculated, taking into consideration the effect of T1 spin decoupling. Explicit expressions for line broadening and shift were derived for the system AX ⇄ BY and in one limiting case also for AmXn ⇄ BmYn, under the conditions where Swift and Connick's equations for single-spin systems are applicable.

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U2 - 10.1016/0022-2364(77)90175-5

DO - 10.1016/0022-2364(77)90175-5

M3 - מאמר

AN - SCOPUS:49449121797

VL - 26

SP - 291

EP - 300

JO - Journal of Magnetic Resonance (1969)

JF - Journal of Magnetic Resonance (1969)

SN - 0022-2364

IS - 2

ER -

The effect of T₁ spin decoupling and chemical exchange on the NMR spectra of first-order multiplets

Abstract

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