The effect of a mild base on curcumin in methanol and ethanol

Yuval Erez, Itay Presiado, Rinat Gepshtein, Dan Huppert*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Steady-state and time-resolved emission techniques were employed to study the effect of acetate, a mild base, on the luminescence of curcumin in methanol and ethanol. We found that the steady-state emission intensity as well as the average fluorescence decay time are reduced by a factor of 5 when the acetate concentration is raised to about 1.8 M. We attribute this large effect to an excited-state proton transfer (ESPT) from the acidic groups of curcumin to the acetate anion. We analyze the experimental data in terms of an ESPT reaction occurring between a photoacid and a base.

Original languageEnglish
Pages (from-to)2039-2048
Number of pages10
JournalJournal of Physical Chemistry A
Volume116
Issue number9
DOIs
StatePublished - 8 Mar 2012

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