TY - JOUR
T1 - The binding of tin atoms to ammonia. A mössbauer study
AU - Pasternak, M.
AU - Barrett, P. H.
N1 - Funding Information:
* Work supported m part by ths k~r~onal Scisnce rlon *-Supported m part by The Israel Commlssron Rexarch
PY - 1981/2/15
Y1 - 1981/2/15
N2 - Mössbauer studies were performed with 119Sn atoms embedded in solid NH3 in the temperature range 14-80 K. The quadrupole-split spectrum with AΔEQ = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO3 indicates formation of a singly bound, covalent SnNH3 molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.
AB - Mössbauer studies were performed with 119Sn atoms embedded in solid NH3 in the temperature range 14-80 K. The quadrupole-split spectrum with AΔEQ = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO3 indicates formation of a singly bound, covalent SnNH3 molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.
UR - http://www.scopus.com/inward/record.url?scp=49049151119&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(81)85578-9
DO - 10.1016/0009-2614(81)85578-9
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AN - SCOPUS:49049151119
SN - 0009-2614
VL - 78
SP - 174
EP - 176
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1
ER -