The binding of tin atoms to ammonia. A mössbauer study

M. Pasternak; P. H. Barrett

doi:10.1016/0009-2614(81)85578-9

The binding of tin atoms to ammonia. A mössbauer study

M. Pasternak^*, P. H. Barrett

^*Corresponding author for this work

School of Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

Abstract

Mössbauer studies were performed with ¹¹⁹Sn atoms embedded in solid NH₃ in the temperature range 14-80 K. The quadrupole-split spectrum with AΔE_Q = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO₃ indicates formation of a singly bound, covalent SnNH₃ molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.

Original language	English
Pages (from-to)	174-176
Number of pages	3
Journal	Chemical Physics Letters
Volume	78
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(81)85578-9
State	Published - 15 Feb 1981

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title = "The binding of tin atoms to ammonia. A m{\"o}ssbauer study",

abstract = "M{\"o}ssbauer studies were performed with 119Sn atoms embedded in solid NH3 in the temperature range 14-80 K. The quadrupole-split spectrum with AΔEQ = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO3 indicates formation of a singly bound, covalent SnNH3 molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.",

author = "M. Pasternak and Barrett, {P. H.}",

note = "Funding Information: * Work supported m part by ths k~r~onal Scisnce rlon *-Supported m part by The Israel Commlssron Rexarch",

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AU - Pasternak, M.

AU - Barrett, P. H.

N1 - Funding Information: * Work supported m part by ths k~r~onal Scisnce rlon *-Supported m part by The Israel Commlssron Rexarch

PY - 1981/2/15

Y1 - 1981/2/15

N2 - Mössbauer studies were performed with 119Sn atoms embedded in solid NH3 in the temperature range 14-80 K. The quadrupole-split spectrum with AΔEQ = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO3 indicates formation of a singly bound, covalent SnNH3 molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.

AB - Mössbauer studies were performed with 119Sn atoms embedded in solid NH3 in the temperature range 14-80 K. The quadrupole-split spectrum with AΔEQ = 2.72(2) mm/s and isomer shift = +2.52(2) mm/s with respect to BaSnO3 indicates formation of a singly bound, covalent SnNH3 molecule. From the temperature dependence of the recoil-free fraction, its force constant in sohd ammonia is derived.

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JF - Chemical Physics Letters

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The binding of tin atoms to ammonia. A mössbauer study

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