TY - JOUR
T1 - Tetrazole-bridged manganese coordination polymer as high-energy material
AU - Friedman, Yoel
AU - Goldberg, Israel
N1 - Publisher Copyright:
© 2017 Elsevier Ltd
PY - 2018/1/8
Y1 - 2018/1/8
N2 - Metal organic frameworks (MOFs) containing nitrogen-rich organic linkers and light-metal ions which exhibit remarkable thermal stability and shock resistivity, can be considered as potential high energetic materials. This work presents a three-dimensional framework MOF structure with manganese and sodium ions as the connecting nodes and N,N-bis(tetrazol-5-yl)amine (bta) di-anionic ligands as the organic linker, generated in-situ through solvothermal synthesis. This solid is considerably robust, and it shows attractive energetic performance as estimated by sensitivity tests and semi-empirical calculations of its detonation properties.
AB - Metal organic frameworks (MOFs) containing nitrogen-rich organic linkers and light-metal ions which exhibit remarkable thermal stability and shock resistivity, can be considered as potential high energetic materials. This work presents a three-dimensional framework MOF structure with manganese and sodium ions as the connecting nodes and N,N-bis(tetrazol-5-yl)amine (bta) di-anionic ligands as the organic linker, generated in-situ through solvothermal synthesis. This solid is considerably robust, and it shows attractive energetic performance as estimated by sensitivity tests and semi-empirical calculations of its detonation properties.
KW - 3D coordination polymer
KW - Crystal structure
KW - High-energy material
KW - High-nitrogen content solid
KW - Metal-organic-framework
UR - http://www.scopus.com/inward/record.url?scp=85034737572&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2017.11.010
DO - 10.1016/j.poly.2017.11.010
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AN - SCOPUS:85034737572
SN - 0277-5387
VL - 139
SP - 327
EP - 330
JO - Polyhedron
JF - Polyhedron
ER -