Tetrazole-bridged manganese coordination polymer as high-energy material

Yoel Friedman, Israel Goldberg

Research output: Contribution to journalArticlepeer-review

Abstract

Metal organic frameworks (MOFs) containing nitrogen-rich organic linkers and light-metal ions which exhibit remarkable thermal stability and shock resistivity, can be considered as potential high energetic materials. This work presents a three-dimensional framework MOF structure with manganese and sodium ions as the connecting nodes and N,N-bis(tetrazol-5-yl)amine (bta) di-anionic ligands as the organic linker, generated in-situ through solvothermal synthesis. This solid is considerably robust, and it shows attractive energetic performance as estimated by sensitivity tests and semi-empirical calculations of its detonation properties.

Original languageEnglish
Pages (from-to)327-330
Number of pages4
JournalPolyhedron
Volume139
DOIs
StatePublished - 8 Jan 2018

Keywords

  • 3D coordination polymer
  • Crystal structure
  • High-energy material
  • High-nitrogen content solid
  • Metal-organic-framework

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