TY - JOUR
T1 - Tetra(pyrrolidino)diborane(4), [(C4H8N)2B]2, as a new improved alternative synthetic route to bis(pinacolato)diborane(4) - Crystal structures of the intermediates
AU - Abu Ali, Hijazi
AU - Goldberg, Israel
AU - Srebnik, Morris
PY - 2002
Y1 - 2002
N2 - The compound tetra(pyrrolidino)diborane(4) (3) is an important new and alternative precursor for the preparation and synthesis of bis(pinacolato)diborane(4). The latter is the major intermediate among the diborane derivatives used for many addition and insertion reactions into multiple bonds. The crystal structure of 3 and its precursor, tris(pyrrolidino)borane, 1, were determined. In addition the solvolysis reactions and solution behavior of 3 with alcohols were examined.
AB - The compound tetra(pyrrolidino)diborane(4) (3) is an important new and alternative precursor for the preparation and synthesis of bis(pinacolato)diborane(4). The latter is the major intermediate among the diborane derivatives used for many addition and insertion reactions into multiple bonds. The crystal structure of 3 and its precursor, tris(pyrrolidino)borane, 1, were determined. In addition the solvolysis reactions and solution behavior of 3 with alcohols were examined.
KW - <Solvolysis
KW - Bis(pinacolato)diborane(4)
KW - Boranes
KW - Tetra(pyrrolidino)diborane(4)
KW - Tris(pyrrolidino)borane
UR - http://www.scopus.com/inward/record.url?scp=0036100146&partnerID=8YFLogxK
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AN - SCOPUS:0036100146
SN - 1434-1948
SP - 73
EP - 78
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 1
ER -