@article{62bf40ba2ef44bc4b62612e1fcffe00a,
title = "Ta(V) complexes of a bulky amine tris(phenolate) ligand: Steric inhibition vs. chelate effect",
abstract = "The reactivity of a bulky amine tris(phenolate) ligand toward Ta(NMe 2)5 was investigated. The reaction leading to the final product LigTa(NMe2)2 was slow and proceeded via an unusual dinuclear complex. The X-ray structures of both complexes were solved. Significantly, although the reaction of Ta(OEt)5 with that ligand precursor is slow as well, no dinuclear intermediate is observed during the reaction course.",
keywords = "Amine tris(phenolate) ligands, Chelating ligands, Dinuclear complex, Tantalum",
author = "Stanislav Groysman and Sharon Segal and Israel Goldberg and Moshe Kol and Zeev Goldschmidt",
note = "Funding Information: This research was supported by the Israel Science Foundation founded by the Israel Academy of Sciences and Humanities.",
year = "2004",
month = aug,
doi = "10.1016/j.inoche.2004.06.003",
language = "אנגלית",
volume = "7",
pages = "938--941",
journal = "Inorganic Chemistry Communications",
issn = "1387-7003",
publisher = "Elsevier B.V.",
number = "8",
}