Tantalum(v) complexes of an amine triphenolate ligand: A dramatic difference in reactivity between the two labile positions

Stanislav Groysman; Sharon Segal; Marina Shamis; Israel Goldberg; Moshe Kol; Zeev Goldschmidt; Einat Hayut-Salant

Tantalum(v) complexes of an amine triphenolate ligand: A dramatic difference in reactivity between the two labile positions

Stanislav Groysman, Sharon Segal, Marina Shamis, Israel Goldberg, Moshe Kol^*, Zeev Goldschmidt, Einat Hayut-Salant

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

A tetradentate trianionic amine triphenolate ligand leads to octahedral Ta(v) complexes of C_s-symmetry, in which the two labile positions that are in cis geometry exhibit a dramatic difference in reactivity, the position trans to a phenoxy group being the active one.

Original language	English
Pages (from-to)	3425-3426
Number of pages	2
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	18
State	Published - 2002

Cite this

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title = "Tantalum(v) complexes of an amine triphenolate ligand: A dramatic difference in reactivity between the two labile positions",

abstract = "A tetradentate trianionic amine triphenolate ligand leads to octahedral Ta(v) complexes of Cs-symmetry, in which the two labile positions that are in cis geometry exhibit a dramatic difference in reactivity, the position trans to a phenoxy group being the active one.",

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AU - Goldberg, Israel

AU - Kol, Moshe

AU - Goldschmidt, Zeev

AU - Hayut-Salant, Einat

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Tantalum(v) complexes of an amine triphenolate ligand: A dramatic difference in reactivity between the two labile positions

Abstract

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