Synthesis, spectroscopy, and structures of chiral rhodium(I) corrole complexes

Irena Saltsman; Yael Balazs; Israel Goldberg; Zeev Gross

doi:10.1016/j.molcata.2006.02.030

Synthesis, spectroscopy, and structures of chiral rhodium(I) corrole complexes

Irena Saltsman, Yael Balazs, Israel Goldberg, Zeev Gross^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The easily accessible chiral corrole 1 was metallated by rhodium and isolated with additional ligands of very different electronic and steric properties: two carbonyls, a cyclic diphosphine, and a diene. The diamagnetic rhodium(I) complexes were characterized by multinuclear NMR methods and X-ray crystallography. The diphosphine-coordinated complex 2b was obtained non-racemic, which was further confirmed by circular dichroism.

Original language	English
Pages (from-to)	263-269
Number of pages	7
Journal	Journal of Molecular Catalysis A: Chemical
Volume	251
Issue number	1-2
DOIs	https://doi.org/10.1016/j.molcata.2006.02.030
State	Published - 17 May 2006

Keywords

Corroles
Rhodium complexes
X-ray crystallography

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10.1016/j.molcata.2006.02.030

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title = "Synthesis, spectroscopy, and structures of chiral rhodium(I) corrole complexes",

abstract = "The easily accessible chiral corrole 1 was metallated by rhodium and isolated with additional ligands of very different electronic and steric properties: two carbonyls, a cyclic diphosphine, and a diene. The diamagnetic rhodium(I) complexes were characterized by multinuclear NMR methods and X-ray crystallography. The diphosphine-coordinated complex 2b was obtained non-racemic, which was further confirmed by circular dichroism.",

keywords = "Corroles, Rhodium complexes, X-ray crystallography",

author = "Irena Saltsman and Yael Balazs and Israel Goldberg and Zeev Gross",

note = "Funding Information: This research was supported by the German Israeli Project (DIP, ZG) and the Israel Science Foundation under Grant 254/04 (IG). Funding of IS by the Center for Absorption in Science – Ministry of Immigration – is acknowledged.",

year = "2006",

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AU - Saltsman, Irena

AU - Balazs, Yael

AU - Goldberg, Israel

AU - Gross, Zeev

N1 - Funding Information: This research was supported by the German Israeli Project (DIP, ZG) and the Israel Science Foundation under Grant 254/04 (IG). Funding of IS by the Center for Absorption in Science – Ministry of Immigration – is acknowledged.

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N2 - The easily accessible chiral corrole 1 was metallated by rhodium and isolated with additional ligands of very different electronic and steric properties: two carbonyls, a cyclic diphosphine, and a diene. The diamagnetic rhodium(I) complexes were characterized by multinuclear NMR methods and X-ray crystallography. The diphosphine-coordinated complex 2b was obtained non-racemic, which was further confirmed by circular dichroism.

AB - The easily accessible chiral corrole 1 was metallated by rhodium and isolated with additional ligands of very different electronic and steric properties: two carbonyls, a cyclic diphosphine, and a diene. The diamagnetic rhodium(I) complexes were characterized by multinuclear NMR methods and X-ray crystallography. The diphosphine-coordinated complex 2b was obtained non-racemic, which was further confirmed by circular dichroism.

KW - Corroles

KW - Rhodium complexes

KW - X-ray crystallography

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JF - Journal of Molecular Catalysis A: Chemical

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ER -

Synthesis, spectroscopy, and structures of chiral rhodium(I) corrole complexes

Abstract

Keywords

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