Synthesis, spectroscopy, and structures of chiral rhodium(I) corrole complexes

Irena Saltsman, Yael Balazs, Israel Goldberg, Zeev Gross*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

The easily accessible chiral corrole 1 was metallated by rhodium and isolated with additional ligands of very different electronic and steric properties: two carbonyls, a cyclic diphosphine, and a diene. The diamagnetic rhodium(I) complexes were characterized by multinuclear NMR methods and X-ray crystallography. The diphosphine-coordinated complex 2b was obtained non-racemic, which was further confirmed by circular dichroism.

Original languageEnglish
Pages (from-to)263-269
Number of pages7
JournalJournal of Molecular Catalysis A: Chemical
Volume251
Issue number1-2
DOIs
StatePublished - 17 May 2006

Funding

FundersFunder number
DIP
German Israeli Project
Israel Science Foundation254/04

    Keywords

    • Corroles
    • Rhodium complexes
    • X-ray crystallography

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