Abstract
The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.
Original language | English |
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Pages (from-to) | 13634-13635 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 125 |
Issue number | 45 |
DOIs | |
State | Published - 12 Nov 2003 |