Synthesis of the Elusive (R3P)2MF2 (M = Pd, Pt) Complexes

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Abstract

The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.

Original languageEnglish
Pages (from-to)13634-13635
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number45
DOIs
StatePublished - 12 Nov 2003

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