Synthesis of the Elusive (R3P)2MF2 (M = Pd, Pt) Complexes

Anette Yahav; Israel Goldberg; Arkadi Vigalok

doi:10.1021/ja0377753

Synthesis of the Elusive (R₃P)₂MF₂ (M = Pd, Pt) Complexes

Anette Yahav, Israel Goldberg, Arkadi Vigalok^*

^*Corresponding author for this work

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF₂. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.

Original language	English
Pages (from-to)	13634-13635
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	45
DOIs	https://doi.org/10.1021/ja0377753
State	Published - 12 Nov 2003

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abstract = "The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.",

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N2 - The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.

AB - The synthesis and characterization of previously unknown palladium(II) and platinum(II) difluoro phosphine complexes are described. These complexes can be obtained either via a halide metathesis reaction with AgF in dichloromethane or by reacting the corresponding dimethyl complexes with XeF2. While the Pt(II) complexes can be prepared with both aryl- and alkyl-phosphine ligands, the stability of the Pd(II) complexes is limited to those having cis-oriented trialkyl phosphine ligands.

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Synthesis of the Elusive (R₃P)₂MF₂ (M = Pd, Pt) Complexes

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