Synthesis of ferrocenyl and ruthenocenyl thioamide derivatives using a single-step three-component reaction

Malay Patra; Jeannine Hess; Sandro Konatschnig; Bernhard Spingler; Gilles Gasser

doi:10.1021/om400715m

Synthesis of ferrocenyl and ruthenocenyl thioamide derivatives using a single-step three-component reaction

Malay Patra^*, Jeannine Hess, Sandro Konatschnig, Bernhard Spingler, Gilles Gasser

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The efficient syntheses of various metallocenyl thioamides using a single-step three-component condensation reaction between the commercially available (dimethylaminomethyl)ferrocene or aminomethylferrocene and another organic amine in the presence of elemental sulfur are described. All new organometallic thioamide derivatives were unambiguously characterized by ¹H and ¹³C NMR spectroscopy and mass spectrometry. Furthermore, the structures of five ferrocenyl thioamides determined by X-ray crystallography are presented.

Original language	English
Pages (from-to)	6098-6105
Number of pages	8
Journal	Organometallics
Volume	32
Issue number	20
DOIs	https://doi.org/10.1021/om400715m
State	Published - 28 Oct 2013
Externally published	Yes

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10.1021/om400715m

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abstract = "The efficient syntheses of various metallocenyl thioamides using a single-step three-component condensation reaction between the commercially available (dimethylaminomethyl)ferrocene or aminomethylferrocene and another organic amine in the presence of elemental sulfur are described. All new organometallic thioamide derivatives were unambiguously characterized by 1H and 13C NMR spectroscopy and mass spectrometry. Furthermore, the structures of five ferrocenyl thioamides determined by X-ray crystallography are presented.",

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AU - Patra, Malay

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AU - Konatschnig, Sandro

AU - Spingler, Bernhard

AU - Gasser, Gilles

PY - 2013/10/28

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N2 - The efficient syntheses of various metallocenyl thioamides using a single-step three-component condensation reaction between the commercially available (dimethylaminomethyl)ferrocene or aminomethylferrocene and another organic amine in the presence of elemental sulfur are described. All new organometallic thioamide derivatives were unambiguously characterized by 1H and 13C NMR spectroscopy and mass spectrometry. Furthermore, the structures of five ferrocenyl thioamides determined by X-ray crystallography are presented.

AB - The efficient syntheses of various metallocenyl thioamides using a single-step three-component condensation reaction between the commercially available (dimethylaminomethyl)ferrocene or aminomethylferrocene and another organic amine in the presence of elemental sulfur are described. All new organometallic thioamide derivatives were unambiguously characterized by 1H and 13C NMR spectroscopy and mass spectrometry. Furthermore, the structures of five ferrocenyl thioamides determined by X-ray crystallography are presented.

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Synthesis of ferrocenyl and ruthenocenyl thioamide derivatives using a single-step three-component reaction

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