@article{d9b345e66a9b492bb2e8faf695799768,
title = "Synthesis of a diverse set of phosphorus ligands on solid support and their screening in the Heck reaction",
abstract = "Representative members from five different families of supported phosphine and phosphinite ligands have been prepared from common templates - polymer-bound aminoalcohols. These include β-aminophosphines, N,β-diphosphinoamines, α,β-diphosphinoamines, β-aminophosphinites and N-phosphino-β-aminophosphinites. Representatives of each family of ligands were complexed with Pd(OAc)2 and screened in the Heck reaction of iodo- and bromobenzene. While the reaction of iodoarenes is ligand-independent, the reaction of bromoarenes is ligand-sensitive. The rationale for this behavior is suggested. Lead ligands for the reaction of bromoarenes were determined.",
keywords = "Heck reactions, Phosphorus ligands, Solid-phase synthesis, Supported catalysts",
author = "Amal Mansour and Moshe Portnoy",
note = "Funding Information: This research was supported by the Israel Science Foundation, founded by the Israel Academy of Sciences and Humanities. ",
year = "2003",
month = mar,
day = "3",
doi = "10.1016/S0040-4039(03)00113-8",
language = "אנגלית",
volume = "44",
pages = "2195--2198",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Ltd.",
number = "10",
}