TY - JOUR
T1 - Synthesis of 6-dinitroethylene-4, 5, 8-trinitro-5, 6, 7, 8-tetrahydro-4H-imidazo[4, 5-e] furazano[3, 4-b]piperazine
AU - Huo, Huan
AU - Wang, Bo Zhou
AU - Lian, Peng
AU - Lai, Wei Peng
AU - Li, Hui
AU - Ge, Zhong Xue
PY - 2014/4
Y1 - 2014/4
N2 - A novel energetic compound, 6-dinitroethylene-4, 5, 8-trinitro-5, 6, 7, 8-tetrahydro-4H-imidazo[4, 5-e] furazano[3, 4-b] piperazine (PNEIFP), was designed and synthesized from glyoxal and FOX-7 by two cyclizations and nitration. In addition, some properties of PNEIFP were calculated by Gaussian 09 program and VLW formula. The results show that its density is 2.02 g·cm-3, and the detonation velocity is 9681.0 m·s-1, and the enthalpy of formation is 724.1 kJ·mol-1. PNEIFP easily decomposes at room temperature.
AB - A novel energetic compound, 6-dinitroethylene-4, 5, 8-trinitro-5, 6, 7, 8-tetrahydro-4H-imidazo[4, 5-e] furazano[3, 4-b] piperazine (PNEIFP), was designed and synthesized from glyoxal and FOX-7 by two cyclizations and nitration. In addition, some properties of PNEIFP were calculated by Gaussian 09 program and VLW formula. The results show that its density is 2.02 g·cm-3, and the detonation velocity is 9681.0 m·s-1, and the enthalpy of formation is 724.1 kJ·mol-1. PNEIFP easily decomposes at room temperature.
KW - 6-dinitroethylene-4, 5, 8-trinitro-5, 6, 7, 8-tetrahydro-4H-imidazo[4, 5-e] furazano[3, 4-b]piperazine
KW - Organic chemistry
KW - Performance
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=84900476760&partnerID=8YFLogxK
U2 - 10.3969/j.issn.1006-9941.2014.02.031
DO - 10.3969/j.issn.1006-9941.2014.02.031
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AN - SCOPUS:84900476760
SN - 1006-9941
VL - 22
SP - 274
EP - 275
JO - Hanneng Cailiao/Chinese Journal of Energetic Materials
JF - Hanneng Cailiao/Chinese Journal of Energetic Materials
IS - 2
ER -