Synthesis and properties of a corrole with small and electron-withdrawing substitutents, 5, 15-bis(trifluoromethyl)-10-pentafluorophenylcorrole

Ruth Goldschmidt, Israel Goldberg, Yael Balazs, Zeev Gross

Research output: Contribution to journalArticlepeer-review

Abstract

Several methodologies for the synthesis of corroles that carry minimal-sized electron-withdrawing substituents at the meso-C atoms were investigated; of these the one based on dypyrromethane/aldehyde condensation was fruitful. The new corrole with one C6F5 and two CF 3 groups, as well as its cobalt(III) complex, were fully characterized by spectroscopy and X-ray crystallography.

Original languageEnglish
Pages (from-to)76-86
Number of pages11
JournalJournal of Porphyrins and Phthalocyanines
Volume10
Issue number2
DOIs
StatePublished - 2006

Keywords

  • Corroles
  • NMR
  • Synthesis
  • X-ray crystallography

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