Synthesis and cascade reactions of diallenyl α-disulfones and sulfinyl sulfones

Samuel Braverman, Marina Cherkinsky, Israel Goldberg, Milon Sprecher

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis and reactivity of diallenic α-disulfones and diallenic sulfinyl sulfones are described. Both types of compound exhibit enhanced reactivity relative to their saturated counterparts, and react spontaneously at low temperature, upon preparation, to yield novel and functionalized bicyclic products. Possible mechanisms for their multi-step rearrangements are suggested.

Original languageEnglish
Pages (from-to)6713-6716
Number of pages4
JournalTetrahedron Letters
Volume48
Issue number38
DOIs
StatePublished - 17 Sep 2007

Keywords

  • Allenes
  • Sulfinyl sulfones
  • Tandem reaction
  • α-Disulfones
  • γ-Sultines
  • γ-Sultones

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