Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates

Furong Guo; Cheng Chen; Kangcai Wang; Qinghua Zhang; Zhien Lin

doi:10.1021/acs.inorgchem.6b01341

Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates

Furong Guo, Cheng Chen, Kangcai Wang, Qinghua Zhang^*, Zhien Lin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A series of open-framework metal oxalates (metal = Zn, Co, Mn, Bi, In) were prepared under solvent-free conditions by a supramolecular templating approach. These compounds have cationic, anionic, and neutral frameworks with pore apertures ranging from small 8-membered rings (8 MRs) to extra-large 16 and 20 MRs. The zinc oxalate exhibits a proton conductivity of 2.6 × 10^-3 S cm^-1 at 60 °C under 98% relative humidity.

Original language	English
Pages (from-to)	7817-7819
Number of pages	3
Journal	Inorganic Chemistry
Volume	55
Issue number	16
DOIs	https://doi.org/10.1021/acs.inorgchem.6b01341
State	Published - 15 Aug 2016
Externally published	Yes

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10.1021/acs.inorgchem.6b01341

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title = "Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates",

abstract = "A series of open-framework metal oxalates (metal = Zn, Co, Mn, Bi, In) were prepared under solvent-free conditions by a supramolecular templating approach. These compounds have cationic, anionic, and neutral frameworks with pore apertures ranging from small 8-membered rings (8 MRs) to extra-large 16 and 20 MRs. The zinc oxalate exhibits a proton conductivity of 2.6 × 10-3 S cm-1 at 60 °C under 98% relative humidity.",

author = "Furong Guo and Cheng Chen and Kangcai Wang and Qinghua Zhang and Zhien Lin",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

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doi = "10.1021/acs.inorgchem.6b01341",

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AU - Wang, Kangcai

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AU - Lin, Zhien

PY - 2016/8/15

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AB - A series of open-framework metal oxalates (metal = Zn, Co, Mn, Bi, In) were prepared under solvent-free conditions by a supramolecular templating approach. These compounds have cationic, anionic, and neutral frameworks with pore apertures ranging from small 8-membered rings (8 MRs) to extra-large 16 and 20 MRs. The zinc oxalate exhibits a proton conductivity of 2.6 × 10-3 S cm-1 at 60 °C under 98% relative humidity.

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Supramolecular Templating Approach for the Solvent-Free Synthesis of Open-Framework Metal Oxalates

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