TY - JOUR
T1 - Supramolecular design of coordination complexes of silver(I) with polyimine ligands
T2 - Synthesis, materials characterization, and structure of new polymeric and oligomeric materials
AU - Patra, Goutam Kumar
AU - Goldberg, Israel
PY - 2003/5
Y1 - 2003/5
N2 - A series of new coordination polymers and oligomers of polyimine ligands with silver(I) ions have been synthesized and characterized by single-crystal X-ray diffraction studies, elemental analysis, IR, UV-Vis, and NMR spectroscopy. They represent discrete dinuclear Ag(I) complexes, one-dimensional polymers, and two-dimensional polymeric assemblies, depending on the chosen type, functionality, and denticity of the bridging ligands. Trigonal, tetrahedral, and pseudo-tetrahedral, as well as the more common linear coordination motifs of the silver(I) ions, have been observed, demonstrating the high versatility in the supramolecular design of such hybrid organic - inorganic materials.
AB - A series of new coordination polymers and oligomers of polyimine ligands with silver(I) ions have been synthesized and characterized by single-crystal X-ray diffraction studies, elemental analysis, IR, UV-Vis, and NMR spectroscopy. They represent discrete dinuclear Ag(I) complexes, one-dimensional polymers, and two-dimensional polymeric assemblies, depending on the chosen type, functionality, and denticity of the bridging ligands. Trigonal, tetrahedral, and pseudo-tetrahedral, as well as the more common linear coordination motifs of the silver(I) ions, have been observed, demonstrating the high versatility in the supramolecular design of such hybrid organic - inorganic materials.
UR - http://www.scopus.com/inward/record.url?scp=0141627630&partnerID=8YFLogxK
U2 - 10.1021/cg034011q
DO - 10.1021/cg034011q
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AN - SCOPUS:0141627630
SN - 1528-7483
VL - 3
SP - 321
EP - 329
JO - Crystal Growth and Design
JF - Crystal Growth and Design
IS - 3
ER -