Substituent-dependent formation of organotransition-metal bimetallic calix[4]arene inclusion complexes

Ella Bukhaltsev; Israel Goldberg; Arkadi Vigalok

doi:10.1021/om049568x

Substituent-dependent formation of organotransition-metal bimetallic calix[4]arene inclusion complexes

Ella Bukhaltsev, Israel Goldberg, Arkadi Vigalok^*

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Reaction of 1,3-di-O-substituted calixarene ligands with Et₂Zn gives new organotransition-metal bimetallic calix[4]arene inclusion complexes when the substituent is larger than methyl. The resulting complexes show strong interactions between the incorporated organometallic fragment and the Hydrophobic cavity of the calixarene group.

Original language	English
Pages (from-to)	4540-4543
Number of pages	4
Journal	Organometallics
Volume	23
Issue number	20
DOIs	https://doi.org/10.1021/om049568x
State	Published - 27 Sep 2004

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title = "Substituent-dependent formation of organotransition-metal bimetallic calix[4]arene inclusion complexes",

abstract = "Reaction of 1,3-di-O-substituted calixarene ligands with Et2Zn gives new organotransition-metal bimetallic calix[4]arene inclusion complexes when the substituent is larger than methyl. The resulting complexes show strong interactions between the incorporated organometallic fragment and the Hydrophobic cavity of the calixarene group.",

author = "Ella Bukhaltsev and Israel Goldberg and Arkadi Vigalok",

year = "2004",

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T1 - Substituent-dependent formation of organotransition-metal bimetallic calix[4]arene inclusion complexes

AU - Bukhaltsev, Ella

AU - Goldberg, Israel

AU - Vigalok, Arkadi

PY - 2004/9/27

Y1 - 2004/9/27

N2 - Reaction of 1,3-di-O-substituted calixarene ligands with Et2Zn gives new organotransition-metal bimetallic calix[4]arene inclusion complexes when the substituent is larger than methyl. The resulting complexes show strong interactions between the incorporated organometallic fragment and the Hydrophobic cavity of the calixarene group.

AB - Reaction of 1,3-di-O-substituted calixarene ligands with Et2Zn gives new organotransition-metal bimetallic calix[4]arene inclusion complexes when the substituent is larger than methyl. The resulting complexes show strong interactions between the incorporated organometallic fragment and the Hydrophobic cavity of the calixarene group.

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JO - Organometallics

JF - Organometallics

IS - 20

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Substituent-dependent formation of organotransition-metal bimetallic calix[4]arene inclusion complexes

Abstract

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