Structure and electrical conductivity of diazine transition metal complexes

A. Teuerstein*, B. A. Feit, G. Navon

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Polymeric and non-polymeric complexes of 5-ethylpyrimidine, pyrazine, 4-methoxy-5-ethylpyrimidine and 2,2′-bipyrimidine with Cu(I), Cu(II) and Ag(I) were prepared. No complex was formed with 4,6-dimethoxy-5-ethylpyrimidine. The dependence of the type of complex formed on the metallic ion and on the structure of the diazinic ligand is discussed. The polymeric complexes had a composition of metal:ligand = 1:1. The electrical conductivity, in the solid state, of the complexes was measured, and was found to be higher for the polymeric complexes than for the non-polymeric complexes.

Original languageEnglish
Pages (from-to)1055-1059
Number of pages5
JournalJournal of Inorganic and Nuclear Chemistry
Volume36
Issue number5
DOIs
StatePublished - May 1974

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