Steric effects in five-membered rings-V. Synthesis, properties, configuration and conformation of 3,3- and 3,4-diphenylcyclopentanols

A. Warshawsky; B. Fuchs

doi:10.1016/0040-4020(69)80005-0

Steric effects in five-membered rings-V. Synthesis, properties, configuration and conformation of 3,3- and 3,4-diphenylcyclopentanols

A. Warshawsky, B. Fuchs^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of the stereoisomers of the title compounds, their partially deuterated analogues and corresponding dicyclohexyl derivatives are presented. Assignments of configuration and attempts of conformational analysis are made based on the outcome of various reduction procedures, intramolecular H-bond and NMR spectroscopic studies. Oxidation rate measurements of the alcohols and equilibration of stereoisomers are also described.

Original language	English
Pages (from-to)	2633-2646
Number of pages	14
Journal	Tetrahedron
Volume	25
Issue number	13
DOIs	https://doi.org/10.1016/0040-4020(69)80005-0
State	Published - 1969
Externally published	Yes

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10.1016/0040-4020(69)80005-0

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abstract = "The synthesis and characterization of the stereoisomers of the title compounds, their partially deuterated analogues and corresponding dicyclohexyl derivatives are presented. Assignments of configuration and attempts of conformational analysis are made based on the outcome of various reduction procedures, intramolecular H-bond and NMR spectroscopic studies. Oxidation rate measurements of the alcohols and equilibration of stereoisomers are also described.",

author = "A. Warshawsky and B. Fuchs",

year = "1969",

doi = "10.1016/0040-4020(69)80005-0",

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AU - Fuchs, B.

PY - 1969

Y1 - 1969

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AB - The synthesis and characterization of the stereoisomers of the title compounds, their partially deuterated analogues and corresponding dicyclohexyl derivatives are presented. Assignments of configuration and attempts of conformational analysis are made based on the outcome of various reduction procedures, intramolecular H-bond and NMR spectroscopic studies. Oxidation rate measurements of the alcohols and equilibration of stereoisomers are also described.

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Steric effects in five-membered rings-V. Synthesis, properties, configuration and conformation of 3,3- and 3,4-diphenylcyclopentanols

Abstract

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