Steric effects in 5-membered rings-VIII. A conformational analytical study of cis- and trans-1,3-dichlorocyclopentane

Benzion Fuchs; Pablo S. Wechsler

doi:10.1016/0040-4020(77)80432-8

Steric effects in 5-membered rings-VIII. A conformational analytical study of cis- and trans-1,3-dichlorocyclopentane

Benzion Fuchs^*, Pablo S. Wechsler

^*Corresponding author for this work

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A study of the title systems was performed using theoretical calculations, dipole moments (experimental and calculated) and NMR spectroscopy. The results were discussed in the light of literature data on related systems. It was concluded that a multitude of conformations occur in a potential well for the cis-isomer and that for the trans-one, an even flatter and more variegated distribution in a double minimum is indicated.

Original language	English
Pages (from-to)	57-64
Number of pages	8
Journal	Tetrahedron
Volume	33
Issue number	1
DOIs	https://doi.org/10.1016/0040-4020(77)80432-8
State	Published - 1977

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10.1016/0040-4020(77)80432-8

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abstract = "A study of the title systems was performed using theoretical calculations, dipole moments (experimental and calculated) and NMR spectroscopy. The results were discussed in the light of literature data on related systems. It was concluded that a multitude of conformations occur in a potential well for the cis-isomer and that for the trans-one, an even flatter and more variegated distribution in a double minimum is indicated.",

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AB - A study of the title systems was performed using theoretical calculations, dipole moments (experimental and calculated) and NMR spectroscopy. The results were discussed in the light of literature data on related systems. It was concluded that a multitude of conformations occur in a potential well for the cis-isomer and that for the trans-one, an even flatter and more variegated distribution in a double minimum is indicated.

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Steric effects in 5-membered rings-VIII. A conformational analytical study of cis- and trans-1,3-dichlorocyclopentane

Abstract

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