Static and dynamic electrolyte effects on excited large dipole solvation: high dielectric constant solvents

V. Ittah; D. Huppert

doi:10.1016/0009-2614(90)87242-J

Static and dynamic electrolyte effects on excited large dipole solvation: high dielectric constant solvents

V. Ittah, D. Huppert

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We report on an incresae in the steady-state fluorescence Stokes shift of coumarin 153 when LiClO₄ is added to polar solvents. A new relaxation process is observed in the presence of the electrolyte which is realted to the ionic atmosphere relaxation around the large dipole created in the excited state.

Original language	English
Pages (from-to)	496-502
Number of pages	7
Journal	Chemical Physics Letters
Volume	173
Issue number	5-6
DOIs	https://doi.org/10.1016/0009-2614(90)87242-J
State	Published - 19 Oct 1990

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title = "Static and dynamic electrolyte effects on excited large dipole solvation: high dielectric constant solvents",

abstract = "We report on an incresae in the steady-state fluorescence Stokes shift of coumarin 153 when LiClO4 is added to polar solvents. A new relaxation process is observed in the presence of the electrolyte which is realted to the ionic atmosphere relaxation around the large dipole created in the excited state.",

author = "V. Ittah and D. Huppert",

year = "1990",

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doi = "10.1016/0009-2614(90)87242-J",

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AU - Ittah, V.

AU - Huppert, D.

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N2 - We report on an incresae in the steady-state fluorescence Stokes shift of coumarin 153 when LiClO4 is added to polar solvents. A new relaxation process is observed in the presence of the electrolyte which is realted to the ionic atmosphere relaxation around the large dipole created in the excited state.

AB - We report on an incresae in the steady-state fluorescence Stokes shift of coumarin 153 when LiClO4 is added to polar solvents. A new relaxation process is observed in the presence of the electrolyte which is realted to the ionic atmosphere relaxation around the large dipole created in the excited state.

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JF - Chemical Physics Letters

SN - 0009-2614

IS - 5-6

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Static and dynamic electrolyte effects on excited large dipole solvation: high dielectric constant solvents

Abstract

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