Stable Free Radicals. 7. 1-Alkyl-4-carbomethoxypyridinyls

Edward M. Kosower, Avraham Teuerstein, Harold P. Waits, Leroy C. Butler

Research output: Contribution to journalArticlepeer-review

Abstract

The synthesis of the l-tert-butyl-4-carbomethoxypyridinyl radical is described and its properties are compared with the corresponding l-methyl, 1-ethyl and 1-isopropyl radicals. Although the tert-butyl radical appears to be the most stable in pure form and less susceptible to π-mer formation, its chemical reactivity toward bromochloromethane is very similar to that of the other 1-alkyl radicals. The nature of the products of reaction of 1-isopropyl-4-carbomethoxypyridinyl with bromochloromethane has been elucidated.

Original languageEnglish
Pages (from-to)800-804
Number of pages5
JournalJournal of Organic Chemistry
Volume43
Issue number5
DOIs
StatePublished - 1978

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